Cross-coupling reactions of organosilicon compounds: new concepts and recent advances.
نویسندگان
چکیده
This review highlights the rapid evolution of the newly-developed class of palladium-catalyzed cross-coupling reactions of organosilicon compounds. A myriad of heteroatom-containing silicon moieties (silyl hydrides, siletanes, silanols, silyl ethers, orthosiliconates, di- and polysiloxanes and pyridylsilanes) undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groups into organic molecules and the range of organic electrophiles that can be used are emphasized.
منابع مشابه
Palladium-catalyzed cross-coupling reactions occupy a unique status among methods for the construction of carbon– carbon bonds. The well-established Stille–Migita–Kosugi coupling of organostannanes and the Suzuki–Miyaura coupling of organoboron compounds are two reactions
unique status among methods for the construction of carbon– carbon bonds. The well-established Stille–Migita–Kosugi coupling of organostannanes and the Suzuki–Miyaura coupling of organoboron compounds are two reactions that, until recently, have been the “gold-standard” among various palladium-catalyzed coupling reactions. Their wide use and extraordinary synthetic utility have provided the imp...
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عنوان ژورنال:
- Chemical & pharmaceutical bulletin
دوره 50 12 شماره
صفحات -
تاریخ انتشار 2002